The Protection Performance of Polypyrrole Coating Doped with Different Counter Anions for the Corrosion of NiTi Alloy
نویسندگان
چکیده
The electrochemical corrosion behavior of NiTi alloy electrodeposited conductive polypyrrole (PPy) coatings doped with small size sulfate (SO42 ), medium size para-toluene sulfonate (pTS ) and large size dodecylbenzene sulfonate (DBS ) counter anions has been studied by electrochemical measurements and surface analysis. It is demonstrated that PPy coatings inhibit the corrosion of NiTi substrate in chloride solution by shifting the corrosion potential and pitting potential positively and increasing the impedance of corrosion process. The protective performance of PPy coatings for NiTi alloy is in the order: PPy/pTS < PPy/SO4 < PPy/DBS. The protective performance of the doped PPy coatings for NiTi alloy is related to their anions exchange abilities. The worse anion exchange ability PPy coating has, the better protective performance. The increase of solution pH increases the corrosion rate of the coated NiTi substrate.
منابع مشابه
Electrochemical Evaluation of Polyvinyl Butyral Coating Containing Polypyrrole/ZnO Nanocomposite for Corrosion protection of Al Alloy
In this work, polypyrrole/ZnO nanocomposite (PPy/ZnO NC) was produced through synthesis of polypyrrole polymer in the presence of ZnO nanoparticles. The corrosion behavior of polyvinyl butyral coatings without and with different weight percentages of nanocomposite on the surface of 7075 Al alloy was investigated in 3.5% NaCl solution at different immersion times using electrochemical impedance ...
متن کاملDirect Electrosynthesis of Polyaniline–Fe2O3 Nanocomposite Coating on Aluminum Alloy 5052 and Its Corrosion Protection Performance
The synthesis of polyaniline- Fe2O3 nanocomposite coating on aluminum Alloy 5052 (AA5052) surface has been investigated by using the galvanostatic method. The anticorrosion performance of polyaniline-Fe2O3 coating was investigated in 3.5% NaCl solution by the open- circuit potential (OCP), Tafel polarization technique and Electrochemical Impedance Spectroscopy (EIS). The corrosion rate of polya...
متن کاملSynthesis of Polypyrrole/CeO2 Nanocomposite and its Application for Improving the Corrosion Protection of Acrylic Waterborne Coating on Mild Steel
In this work, polypyrrole/CeO2 nanocomposite (NC) was synthesized in the presence of methylorange as a reactive self-degraded soft template. The field emission scanning electron microscopy(FESEM) images indicate that the CeO2 NPs have a nucleus effect and cause a homogenous PPycore–shell type morphology with an encapsulation of the CeO2 core by the PPy shell. The effect ofNC on acrylic waterbor...
متن کاملEffect of Water/Alkoxide Molar Ratio on the Synthesis Process and Electrochemical Behavior of Yttria-doped Zirconia Sol-gel Films
The aim of this work is to synthesize and investigate the performance of yttria-doped zirconia solgel coatings in the chemical corrosion prevention of zircaloy-4 (zirconium alloy) in a 1 N H2SO4 environment. The influence of four different molar ratios of water to alkoxide, namely 1, 4, 12, and 20, on the coating quality and its corrosion prevention performance was investigated. Differential th...
متن کاملEnhanced of Nano-mechanical Properties of NiTi Alloy by Applied Nanostructured Tantalum Nitride Coating with Magnetron Sputtering method
Nowadays, suitable protective properties of tantalum nitride coatings, such as hardness, abrasion resistance and high corrosion resistance lead to increasing its application in medical engineering and improving the biological behavior of titanium and its alloys. In this research, nanostructured tantalum nitride coating was applied on the NiTi alloy by magnetron sputtering method. Then, the ...
متن کامل